An interesting class of problems in geometry concerns tiling or tessellation, in which a surface or three-dimensional space is covered using one or more geometric shapes with no overlaps or gaps in between. One such tessellation problem is the "Kelvin problem," named after Lord Kelvin who solved it, which concerns the "tessellation of space into cells of equal volume with the least surface area." The Kelvin structure, as the solution is now called, is a convex uniform honeycomb structure formed by a bi-truncated octahedron. For nearly one hundred years, the Kelvin structure was thought to be the most efficient form in the context of the Kelvin problem, until Weaire and Phelan came up with an even more efficient form, called "the Weaire-Phelan structure," via computer simulations.
The Weaire-Phelan structure is made of two kinds of cells–a tetrakaidecahedron having two hexagonal and twelve pentagonal phases, and an irregular dodecahedron with pentagonal faces, with the two cells having equal volumes. The structure is formed when 3/4 of the tetrakaidecahedron cells and 1/4 of the dodecahedron cells are arranged in a specific way. In the real world, the Weaire-Phelan structure has been observed only in two instances, namely liquid foam made from a detergent solution and a palladium (Pd)-lead (Pb) alloy. Interestingly, a Weaire-Phelan structure made of organic materials such as polymers has never been constructed.
Now, a group of researchers from Japan has risen to the occasion, developing the first polymeric Weaire-Phelan structure using facile synthetic procedures. This study, led by Prof. Naofumi Naga from Shibaura Institute of Technology, was published online in Scientific Reports on November 9, 2022. The study was done in collaboration with Prof. Tamaki Nakano from Hokkaido university through the Joint Usage/Research Center Program (MEXT).
The team used a network polythiourethane for polymerization-induced phase separation to construct the Weaire-Phelan structure. "The proposed Weaire-Phelan structure has closely packed uniform particles of the order of micrometers; this has never been achieved before. This is the first example of a Weaire-Phelan structure made from a polymer species and of a solid-polymer cubic honeycomb created by polymerization-induced phase separation," explains Prof. Naga, speaking of the team's motivation behind the study.
To synthesize the polymer, the team used a simple polyaddition reaction between two compounds–tetrakis (3-mercaptopropionate) (PEMP) and hexamethylene diisocyanate (HDI). This synthetic method is based on the joint-and-linker concept, in which a multi-functional monomer serves as the joint source monomer and an α,ω-bifunctional monomer serves as the linker source monomer, forming a polymer network. Accordingly, PEMP, a multi-functional primary thiol, served as the "joint" source monomer, and HDI, a diisocyanate, served as the "linker" source monomer. The reaction took place in the presence of triethylamine (TEA), which served as the base catalyst in toluene.
The team produced three samples using monomer concentrations at 25, 30, and 35 wt%, and called them samples 1, 2, and 3, respectively. They found that sample 3 exhibited space-filling polyhedron particles with hexagonal and pentagonal faces on its surface, which corresponds to the polyhedrons of the Weaire-Phelan structure. Further, 3D scanning electron microscopy was used to study the polyhedron structure of sample 3, which revealed structures of space-filling polyhedrons, matching the polyhedrons of the Weaire-Phelan structure exactly.
"The cubic honeycomb proposed by Kelvin was thus formed for the Weaire-Phelan structure in this work. The material synthesized in this work could potentially have applications in photonics, separation, catalysis, nanomedicine, and structural materials based on the new synthetic methodologies and structural concepts. This could open up a new direction of research for the development of advanced materials with unforeseen functions," concludes an excited Prof. Naga.
And we're just as eager to find out!
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Reference
DOI: https://doi.org/10.1038/s41598-022-22058-7
About Shibaura Institute of Technology (SIT), Japan
Shibaura Institute of Technology (SIT) is a private university with campuses in Tokyo and Saitama. Since the establishment of its predecessor, Tokyo Higher School of Industry and Commerce, in 1927, it has maintained "learning through practice" as its philosophy in the education of engineers. SIT was the only private science and engineering university selected for the Top Global University Project sponsored by the Ministry of Education, Culture, Sports, Science and Technology and will receive support from the ministry for 10 years starting from the 2014 academic year. Its motto, "Nurturing engineers who learn from society and contribute to society," reflects its mission of fostering scientists and engineers who can contribute to the sustainable growth of the world by exposing their over 8,000 students to culturally diverse environments, where they learn to cope, collaborate, and relate with fellow students from around the world.
Website: https://www.shibaura-it.ac.jp/en/
About Professor Naofumi Naga from SIT, Japan
Naofumi Naga is a Professor in the Department of Applied Chemistry at the Shibaura Institute of Technology in Japan. He received his Ph.D. in Polymer Chemistry from the Tokyo Institute of Technology, Japan. His research interests lie in polymer chemistry with a focus on polymer synthesis and characterization. He has 161 publications with 2768 citations to his name.
Funding Information
This research was partially supported by JSPS KAKENHI grant number 24550261, MEXT/JSPS KAKENHI grant number JP 19H02759, and Japan Science and Technology Agency grand number JPMJTMl9E4.
