Researchers from the University of Oxford have for the first time discovered an approach to electrically switch organic LEDs (OLEDs) to emit either left- or right-handed circularly polarized light without changing the light-emitting molecules. This could be useful for a range of technological applications, from more energy efficient OLED displays, to optical information transfer. They describe their results in a study published today (26 Nov) in Nature Photonics .
Usually, the handedness of such circularly polarized light from LEDs is controlled by choosing a particular mirror image form of the light-emitting molecule within the device. These mirror image forms are referred to as left- or right-handed, or chiral, which can be thought of as similar to choosing whether a corkscrew twists to the left or to the right. The handedness of the molecule controls the handedness of the emitted light. This necessarily requires access to both mirror image forms of the molecule, which are complex and expensive to prepare.
Now, a team from the University of Oxford have shown for the first time that both left- and right-handed forms of circularly polarized light can be produced by just one mirror form of the molecule in an OLED.
The researchers managed to switch the handedness of the emitted light electrically, without changing the material itself. They achieved this by designing emitting materials that show unusual effects on circularly polarized light, together with careful control of the way the electronic charges recombine inside the device. Depending on whether charge transport is balanced or unbalanced, the device produces one or the other mirror form of circularly polarized light. Key to this unexpected outcome is the use of an organic polymeric emitting material in the device that self-assemblies into a highly twisted structure.
