Research extends life of rechargeable batteries

Western-led research may ‘charge up’ consumers by addressing their frequent complaint that rechargeable batteries gradually hold less charge over time. The solution to longer battery life, researchers contend, may be found in adding a carbon-based layer to lithium-ion rechargeable batteries.

“We added a thin layer of carbon coating to the aluminum foil that conducts electric current in rechargeable batteries,” explained Xia Li, a Mitacs Postdoctoral Fellow in the Faculty of Engineering and lead researcher of the study. “It was a small change, but we found the carbon coating protected the aluminum foil from corrosion of electrolyte in both high voltage and high energy environments – boosting the battery capacities up to 50 per cent more than batteries without the carbon coating.”

Li is part of Western’s Advanced Materials for Clean Energy Group led by Engineering professor Xueliang (Andy) Sun.

Western researchers collaborated with 3M Canada, which provided the carbon coating, and the Canadian Light Source (CLS) at the University of Saskatchewan, which provided the synchrotron light required to test the coating.

Aluminum foil is commonly used on the cathode as current collector where electricity leaves the battery of rechargeable lithium ion batteries. This foil has high electronic conductivity and is lightweight and low cost, but the new generation of batteries brings new challenges to the current collectors, which will need even more chemical stability to protect against the corrosion of electrolyte in the cathode. This will help to maintain long battery life cycles.

Rather than find an entirely new material for cathodes, the Western team tested a super-thin coating produced by 3M Canada, called graphene.

Li sees electric vehicles as a key application for better battery technologies, and is excited about the green energy sources batteries can support in general.

“We are very interested in using batteries to develop a new clean energy society,” Li said. “Oil is not a good long-term choice for humans and when we convert to green energy sources, we need clean secondary energy storage devices.”

Because of its conductivity, flexibility, and availability, this thin carbon coating could become a key tool for developing battery technologies for a greener future. For years, Sun’s group has harnessed the power of synchrotron light at the CLS to help develop more advanced batteries.

“Without synchrotron radiation, it’s very hard for us to understand the chemistry and electrochemistry reactions of batteries. But synchrotron techniques can tell us what kind of reactions happen and offer very important guidance for the design of future battery materials,” Sun said.

The team used extremely bright X-rays at the CLS to identify what chemical changes occur on delicate battery surfaces while they are operating. Their analysis showed that the coating is effective in both high-voltage and high-energy environments, which would be important for applications like electric vehicles.

The study, Suppressing Corrosion of Aluminum Foils via Highly Conductive Graphene-like Carbon Coating in High-Performance Lithium-Based Batteries, was recently published in ACS Applied Materials and Interfaces.

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