New Resources From Waste Products

TUM

Across the globe, researchers are striving to develop sustainable methods for cleaning contaminated wastewater. At the TUM School of Natural Sciences, doctoral researcher Yixiao Zhang is creating nanoparticles that act as highly efficient catalysts, transforming waste products into new and valuable resources like the fertilizer urea.

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How can harmful substances be converted into useful materials - while using as little energy as possible? This question drives electrochemist Yixiao Zhang. Originally from China, she came to Germany in 2013 to complete her International Baccalaureate at the International School of Düsseldorf. She went on to earn a Bachelor's degree in Chemistry in the Netherlands and a Master's in Chemical Biotechnology at the TUM Campus Straubing. Since April 2024, Yixiao has been pursuing her PhD in the research group of Prof. Dr. Aliaksandr Bandarenka, Professor of Physics of Energy Conversion and Storage .

From energy-intensive to energy-efficient

In her doctoral research, Yixiao investigates new approaches to make chemical processes more energy-efficient. The energy conversion processes she studies rely on catalysts - substances that accelerate chemical reactions without being consumed in the process. Her goal: to remove pollutants such as nitrates and bicarbonates from wastewater which poses a serious threat to ecosystems and drinking water. Simultaneously she wants to convert them into valuable compounds like urea, a key component in fertilizers. Compared to other nitrogen fertilizers, urea is the most efficient solid one available and is used worldwide for food production. So it is needed in large amounts.

Conventional urea production by industrial Bosch-Meiser process is both energy-intensive and carbon-emitting. A promising alternative is electrochemical synthesis , which uses electricity instead of heat and high pressure to drive chemical reactions. This method can significantly reduce both energy consumption and CO2 emissions. However, controlling the process to produce mainly urea - rather than unwanted by-products - remains a major challenge.

Designing smarter catalysts for higher selectivity

Catalysts can help to shift these reactions towards urea production. Yixiao designs such catalysts that are only a few nanometers in size. "The goal of my research is to establish design principles for catalysts that not only increase selectivity toward urea but also enable sustainable nitrogen utilization via an upcycling process," she explains. She focuses on copper-based bimetallic catalysts, fine-tuning their structure to stabilize reaction intermediates that promote urea formation and minimize energy losses.

In the future, these highly efficient catalysts could help remove nitrates from wastewater while producing valuable resources such as urea - saving energy, reducing emissions, and conserving natural resources at the same time.

Making science playful and accessible

Set-up of the escape room game
Yixiao with Silke Mayerl-Kink and Caroline Zörlein (from left to right) from the Cluster of Excellence "e-conversion", in action during the escape room game "Escape from Carbonia".

Beyond her lab work, Yixiao is passionate about science communication and enjoys sharing her enthusiasm for chemistry with the public. Together with colleagues from the Cluster of Excellence e-conversion and an interdisciplinary team at TUM, she co-developed the interactive escape-room game "Escape from Carbonia" . The game offers a playful way to explore renewable energy research and won the 2025 University Competition organized by "Wissenschaft im Dialog" . At the Deutsches Museum and other public venues such as the Kunstareal München, Yixiao and her team are now bringing science closer to people - and showing that research can be exciting, engaging, and fun.

Yixiao Zhang, PhD student in the research group Physics of Energy Conversion and Storage. Astrid Eckert / TUM
Yixiao Zhang, PhD student in the research group Physics of Energy Conversion and Storage of Prof. Aliaksandr Bandarenka. She designs catalysts for electrochemical reactions.
Yixiao Zhang uses scanning electron microscopy to visualize the surface morphology of bimetallic samples that can be used as catalysts. Astrid Eckert / TUM
She works with the Scanning Electron Microscopy with Energy-Dispersive X-ray Spectroscopy (SEM-EDX mapping). She uses it to visualize the surface morphology of bimetallic samples that can be used as catalysts. At the same time, Yixiao identifies and maps the spatial distribution of metallic elements in the samples. This helps determine, for example, how the metals are mixed or detect compositional variations.
Yixiao places a sample in the microscope. Astrid Eckert / TUM
Yixiao places a sample in the microscope. The samples were mounted onto aluminum stubs with conductive carbon tape to ensure proper grounding and stability. The mounted specimens are then transferred under vacuum conditions from the load lock chamber (shown in the image) to the main chamber of the scanning electron microscope (SEM) to prevent contamination and maintain imaging conditions.
Yixiao Zhang during the experiment setup. She investigates reaction mechanisms of the electrode material. Astrid Eckert / TUM
For the experimental setup the researcher assembles her electrochemical cell fitted with a rotation disk electrode. She investigates the reaction mechanisms depending on the surface of the material.
Yixiao Zhang places the crystal inside the rotation disk electrode adapter. Then, she attaches it to the rotation shaft. Astrid Eckert / TUM
Yixiao places the crystal inside the rotation disk electrode adapter. Then, she attaches it to the rotation shaft.
Yixiao Zhang, PhD student in the research group Physics of Energy Conversion and Storage. Astrid Eckert / TUM
Yixiao Zhang, PhD student in the research group Physics of Energy Conversion and Storage of Prof. Aliaksandr Bandarenka. She designs catalysts for electrochemical reactions.
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