Using Phosphorus Nanolayers for Fast-Charge Battery Enhancement

Abstract

Achieving fast-charging lithium-ion batteries (LIBs) with reliable cyclability remains a significant challenge. In this study, we investigate the use of phosphorus nanolayers as a strategy to enhance the lithiation kinetics and performance of graphite-based composites without inducing lithium (Li) plating on the electrode surface, increasing the delivery capacity. In particular, operando optical microscopy reveals that during fast charging, the concentrated Li-ion flux near the graphite electrode surface impedes Li-ion permeation into the bulk, leading to nonuniform lithiation. In contrast, our designed graphite-P/C composite electrodes exhibit a well-dispersed LiC6 phase volume fraction throughout the electrodes, indicating the homogeneous lithiation of graphite. Our electrodes maintain consistent cycle retention (94.4%) and high Coulombic efficiency (>99.8%) over 1000 cycles at 1C owing to their enhanced reaction kinetics despite their relatively high capacity. Our findings highlight the potential of using phosphorus-based composites as a promising approach for achieving fast-charging LIBs with enhanced performance and safety.

In a major stride towards achieving fast-charging lithium-ion batteries (LIBs) with reliable cyclability, researchers at UNIST have made a groundbreaking discovery. Their study, published in the prestigious ACS Energy Letters, introduces a novel strategy of utilizing phosphorus nanolayers to enhance the lithiation kinetics and performance of graphite-based composites, without compromising safety.

Led by Professor Hyun-Wook Lee from the School of Energy and Chemical Engineering at UNIST, the research team developed a revolutionary graphite-phosphorus composite using a vaporization-condensation method. This composite consists of a porous graphite cathode material coated with red phosphorus and carbon, enabling improved electron and lithium ion conductivity on the graphite surface.

Achieving fast-charging LIBs with reliable cyclability remains a significant challenge, such as nonuniform lithiation, which can lead to performance degradation. However, the newly developed graphite-phosphorus composite electrodes exhibited a well-dispersed LiC6 phase volume fraction throughout the electrodes, indicating a homogenous lithiation process.

One of the remarkable achievements of this breakthrough is the consistent cycle retention of 94.4% and high Coulombic efficiency exceeding 99.8% over 1000 cycles at 1C. These exceptional results are attributed to the enhanced reaction kinetics of the graphite-phosphorus composite electrodes, despite their relatively high capacity.

"Graphite-based cathode materials are expected to dominate the lithium-ion battery market for the next decade," explained Professor Lee. "Our research focuses on improving the energy density and fast-charging capabilities of graphite, which are key factors in the market." He added, "The development of low-cost graphite cathode materials coated with red phosphorus and carbon will significantly meet the demands of the battery industry."

The utilization of red phosphorus, with its low boiling point, allows for uniform vapor deposition on the graphite surface. By carefully controlling the deposition process, the research team successfully achieved a graphite-phosphorus composite with controlled side reactions, leading to enhanced uniformity and stability during fast charging.

Real-time optical microscopy and image processing techniques were employed to observe and analyze the developed composite. The results confirmed the uniform color distribution of the graphite-phosphorus composite during charging, indicating improved lithiation uniformity. The composite also demonstrated exceptional stability, with no resin phase formation observed during fast charging, even after 1,000 cycles or more.

This breakthrough research opens up new possibilities for a wide range of applications, including electric vehicles, aviation, and fast-charging batteries. The cost-effectiveness and superior performance of the graphite-phosphorus composite make it a promising solution to overcome the challenges associated with fast-charging LIBs.

This study was made possible with support through the 2023 Research Fund of UNIST and Individual Basic Science & Engineering Research Program through National Research Foundation of Korea (NRF), funded by the Ministry of Science and ICT (MSIT).

Journal Reference

Min-Ho Kim, Juyoung Kim, Seong-Hyeon Choi, et al., "Mitigating Electrode-Level Heterogeneity Using Phosphorus Nanolayers on Graphite for Fast-Charging Batteries," ACS Energy Lett., (2023).